Coordinatively Unsaturated Metal Centers as Building Blocks for High Coordination Number Metallomesogens
نویسندگان
چکیده
منابع مشابه
Increasing the density of adsorbed hydrogen with coordinatively unsaturated metal centers in metal-organic frameworks.
Storing molecular hydrogen in porous media is one of the promising avenues for mobile hydrogen storage. In order to achieve technologically relevant levels of gravimetric density, the density of adsorbed H2 must be increased beyond levels attained for typical high surface area carbons. Here, we demonstrate a strong correlation between exposed and coordinatively unsaturated metal centers and enh...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2001
ISSN: 1433-7851
DOI: 10.1002/1521-3773(20010105)40:1<242::aid-anie242>3.0.co;2-o